COMPOSITIONAL ANALYSIS OF BIOMER

被引：14

作者：

BELISLE, J ^{[1
]}

MAIER, SK ^{[1
]}

TUCKER, JA ^{[1
]}

机构：

[1] THREE M CO,LIFE SCI SECTOR BIOSCI,3M CTR,ST PAUL,MN 55144

来源：

JOURNAL OF BIOMEDICAL MATERIALS RESEARCH | 1990年 / 24卷 / 12期

关键词：

D O I：

10.1002/jbm.820241204

中图分类号：

R318 [生物医学工程];

学科分类号：

0831 ;

摘要：

Biomer, a segmented polyether polyurethane, has been analyzed via hydrolysis/gas chromatography to determine its composition. In addition to the previously reported 4,4′‐methylene bis(phenyl isocyanate) (MDI), polytetramethylene glycol (PTMO), and ethylenediamine, we now report the presence of diethylamine, 1,3‐diaminocyclohexane and poly(diisopropylaminoethyl methacrylate‐co‐decyl methacrylate), Biomer's cloudy insoluble phase. In addition, a method is presented to characterize the methacrylate additive by molecular weight based on GPC. Also found by chromatography were the antioxidants Santowhite Powder and BHT. XPS shows no Si (silicone) on the Biomer surface, and a total chloride analysis reports no chloride (<0.03%). Time‐of‐flight SIMS data suggest evidence for the methacrylate additive at the surface, and mass spectroscopy can be interpreted as evidence for a diaminocyclohexane. Copyright © 1990 John Wiley & Sons, Inc.

引用

页码：1585 / 1598

页数：14

共 55 条

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