PREPARATION AND PROPERTIES OF CDS/CDTE THIN-FILM SOLAR-CELL PRODUCED BY PERIODIC PULSE ELECTRODEPOSITION TECHNIQUE

被引:25
作者
DAS, SK
MORRIS, GC
机构
[1] Department of Chemistry, University of Queensland, Brisbane
关键词
D O I
10.1016/0927-0248(93)90012-R
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
CdS/CdTe solar cells have been prepared by periodic pulse electrodeposition method. 10.8% efficient cell was made with open circuit voltage (V(oc)) almost-equal-to 753 mV, short-circuit current (J(sc)) almost-equal-to 23.6 mA/cm2 and fill factor (FF) almost-equal-to 0.61. Current-voltage-temperature measurements showed the variation of ideality factor (A) from 1.88 at 344 K to 4.49 at 202 K whereas voltage factor (a) was almost constant above 276 K. The junction transport is possibly dominated by a tunneling mechanism. Capacitance measurements gave the value of diffusion potential as 1.2 eV, ionized charged density as 5.9 X 10(15) cm-3 and number of interface states (N(IS)) as 2.8 X 10(11) cm-2 eV-1 at zero volt bias. Measurements of open circuit voltage (V(OC)) with temperature gave the value of barrier height as 1.42 eV.
引用
收藏
页码:107 / 118
页数:12
相关论文
共 37 条
[31]  
TAVAKOLIAN H, 1988, 20TH P IEEE PHOT SPE, P1608
[32]  
Tyan Y-S., 1982, 16TH P IEEE PHOT SPE, P794
[33]  
Tyan YS, 1980, U.S. Patent, Patent No. [No. 4,207,119, 4207119]
[34]   THE PERIODIC, ELECTROCHEMICAL CODEPOSITION OF CADMIUM AND TELLURIUM [J].
VERBRUGGE, MW ;
TOBIAS, CW .
AICHE JOURNAL, 1987, 33 (04) :628-642
[35]  
Woodcock J.M., 1991, 22ND P IEEE PHOT SPE, P842
[36]  
1987, DOECH100957 NTIS US
[37]  
1989, DOECH1009340 NTIS US, V1