HIGHLY STEREOSELECTIVE ADDITION-REACTIONS OF METALATED TRANS-1,3-DITHIANE-1,3-DIOXIDE TO ALDEHYDES

被引：22

作者：

AGGARWAL, VK ^{[1
]}

FRANKLIN, RJ ^{[1
]}

RICE, MJ ^{[1
]}

机构：

[1] ICI PLC,AGROCHEM,JEALOTTS HILL RES STN,BRACKNELL RG12 6EY,BERKS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 52期

关键词：

D O I：

10.1016/0040-4039(91)80580-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The sodium anion of trans-1,3-dithiane-1,3-dioxide reacts with unhindered aromatic and heteroaromatic aldehydes to give adducts with 95:5 to 97:3 diastereoselectivity.

引用

页码：7743 / 7746

页数：4

共 27 条

[1] Ager D. J., 1987, UMPOLED SYNTHONS, P19
[2] SYNTHESIS, X-RAY CRYSTAL-STRUCTURE, EQUILIBRATION STUDIES AND ANION CHEMISTRY OF TRANS-1,3-DITHIANE 1,3-DIOXIDE
AGGARWAL, VK
DAVIES, IW
FRANKLIN, RJ
MADDOCK, J
MAHON, MF
MOLLOY, KC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (03): : 662 - 664
[3] ADDITIONS OF ALDEHYDES TO METALLATED TRANS-1,3-DITHIANE-S,S-DIOXIDE UNDER CONDITIONS OF KINETIC AND THERMODYNAMIC CONTROL
AGGARWAL, VK
DAVIES, IW
MADDOCK, J
MAHON, MF
MOLLOY, KC
[J]. TETRAHEDRON LETTERS, 1990, 31 (01) : 135 - 138
[4] Brown C, 1990, CHIRALITY DRUG DESIG, P29
[5] CHIRAL ACYL ANION AND ENOLONIUM ION EQUIVALENTS - ASYMMETRIC-SYNTHESIS OF ALPHA-METHOXY-ALDEHYDES
COLOMBO, L
GENNARI, C
SCOLASTICO, C
GUANTI, G
NARISANO, E
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1981, (04): : 1278 - 1283
[6] CHIRAL ACYL ANION EQUIVALENTS - ASYMMETRIC SYNTHESIS OF ALPHA-METHOXYTOLUALDEHYDE
COLOMBO, L
GENNARI, C
SCOLASTICO, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (13) : 591 - 592
[7] Corey E. J., 1989, LOGIC CHEM SYNTHESIS
[8] ATROPISOMERIC SULFUR-COMPOUNDS IN ORGANIC-SYNTHESIS - GENERATION AND REACTIONS OF THE CARBANIONS OF DINAPHTHO[2,1-D-1',2'-F][1,3]DITHIEPINE AND ITS OXIDES
DELOGU, G
DELUCCHI, O
LICINI, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (07) : 411 - 412
[9] Delogu G, 1989, SYNLETT, P28
[10] ASYMMETRIC SYNTHESES BASED ON 1,3-OXATHIANES .1. SCOPE OF THE REACTION
ELIEL, EL
MORRISNATSCHKE, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (10) : 2937 - 2942

← 1 2 3 →