CLEAVAGE OF TIN-CARBON BONDS OF ORGANOSILYLSTANNANE AND ORGANODISTANNANE IN PHOTOINDUCED ELECTRON-TRANSFER REACTIONS AND MASS-SPECTROMETRY

被引：4

作者：

KYUSHIN, S ^{[1
]}

OTANI, S ^{[1
]}

NAKADAIRA, Y ^{[1
]}

OHASHI, M ^{[1
]}

机构：

[1] UNIV ELECTROCOMMUN, DEPT APPL PHYS & CHEM, CHOFU, TOKYO 182, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 01期

关键词：

D O I：

10.1246/cl.1995.29

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Photoalkylation of tetracyanobenzene and benzil with (n-Bu)(3)SnSiMe(3) or (n-Bu)(3)SnSn(n-Bu)(3) proceeds via electron transfer. In these reactions, the Sn-C bond of(n-Bu)(3)SnSiMe(3) and (n-Bu)(3)SnSn(n-Bu)(3) is cleaved in preference to the Sn-Sn and Sn-Sn bonds. Similar cleavage of the Sn-C bond is also observed in mass spectra of these group 14 organometallic compounds.

引用

页码：29 / 30

页数：2

共 23 条

[1]

CLEAVAGE OF CARBON SILICON BONDS IN THE PRESENCE OF SILICON SILICON BONDS BY ELECTRON-TRANSFER REAGENTS [J].

ALLRED, AL ;

SMART, RT ;

VANBEEK, DA .

ORGANOMETALLICS, 1992, 11 (12) :4225-4230

[2]

OXIDATION OF DISTANNANES BY TETRACYANOETHYLENE AND 7,7,8,8-TETRACYANOQUINODIMETHANE [J].

CORNWELL, AB ;

HARRISON, PG ;

RICHARDS, JA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 67 (02) :C43-C44

[3]

SELECTIVE ONE-ELECTRON REDUCTION OF A CATIONIC SUBSTRATE, 10-METHYLACRIDINIUM ION, BY GROUP-4B DIMETALS, ME3SNSNME3, ME3SNGEME3, ME3SNSIME3, VIA RADICAL CHAIN REACTIONS [J].

FUKUZUMI, S ;

KITANO, T ;

MOCHIDA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (08) :3246-3247

[4]

PHOTOINDUCED ELECTRON-TRANSFER REACTION BETWEEN HEXAMETHYLDISILANE AND QUINONES AS STUDIED BY A CIDNP TECHNIQUE [J].

IGARASHI, M ;

UEDA, T ;

WAKASA, M ;

SAKAGUCHI, Y .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 421 (01) :9-19

[5]

ELECTRON-SPIN RESONANCE STUDY OF OXIDATIVE HOMOLYTIC CLEAVAGE OF METAL-METAL AND METAL-CARBON BONDS [J].

KRUSIC, PJ ;

STOKLOSA, H ;

MANZER, LE ;

MEAKIN, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (03) :667-669

[6]

NOVEL SILYLATION OF AROMATIC NITRILES VIA PHOTOINDUCED ELECTRON-TRANSFER [J].

KYUSHIN, S ;

EHARA, Y ;

NAKADAIRA, Y ;

OHASHI, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (05) :279-280

[7]

PHOTOALKYLATION OF ALPHA-DIKETONES WITH TETRAALKYLSTANNANES VIA ELECTRON-TRANSFER [J].

KYUSHIN, S ;

OTANI, S ;

TAKAHASHI, T ;

NAKADAIRA, Y ;

OHASHI, M .

CHEMISTRY LETTERS, 1991, (05) :775-778

[8]

NOVEL ALKYLATION OF AROMATIC NITRILES VIA PHOTOINDUCED ELECTRON-TRANSFER OF GROUP 14 METAL-CARBON SIGMA-DONORS [J].

KYUSHIN, S ;

MASUDA, Y ;

MATSUSHITA, K ;

NAKADAIRA, Y ;

OHASHI, M .

TETRAHEDRON LETTERS, 1990, 31 (44) :6395-6398

[9]

PHOTOSILYLATION OF ELECTRON-DEFICIENT ALKENES BY USE OF DISILANES VIA PHOTOINDUCED ELECTRON-TRANSFER [J].

MIZUNO, K ;

NAKANISHI, K ;

CHOSA, J ;

NGUYEN, T ;

OTSUJI, Y .

TETRAHEDRON LETTERS, 1989, 30 (28) :3689-3692

[10]

PHOTOCHEMICAL CARBON SILICON BOND-FORMING REACTION ON ELECTRON-DEFICIENT ALKENES BY DISILANES AND POLYSILANES VIA PHOTOINDUCED ELECTRON-TRANSFER [J].

MIZUNO, K ;

NAKANISHI, K ;

CHOSA, J ;

OTSUJI, Y .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 473 (1-2) :35-43

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