ELECTRON-DENSITY DISTRIBUTION IN THE BONDS OF A DEWAR BENZENE DERIVATIVE

被引：7

作者：

IRNGARTINGER, H

DEUTER, J

机构：

[1] Organisch-Chemisches Institut, Universität Heidelberg, D-6900

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 02期

关键词：

Difference electron densities / Dewar benzene; derivative;

D O I：

10.1002/cber.19901230219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We determined the difference electron densities [X–X] in the bonds of a Dewar benzene derivative from low temperature X‐ray data (94 K). The density maxima on all bonds are significant. The central bond with an internuclear distance of 1.594 Å has a strong bending character. From the difference densities a bending angle of 28° can be derived. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

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页码：341 / 343

页数：3

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