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ELECTRON-DENSITY DISTRIBUTION IN THE BONDS OF A DEWAR BENZENE DERIVATIVE

被引：7
作者：
IRNGARTINGER, H
DEUTER, J
机构：
[1] Organisch-Chemisches Institut, Universität Heidelberg, D-6900
来源：
CHEMISCHE BERICHTE | 1990年 / 123卷 / 02期
关键词：
Difference electron densities / Dewar benzene; derivative;
D O I：
10.1002/cber.19901230219
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We determined the difference electron densities [X–X] in the bonds of a Dewar benzene derivative from low temperature X‐ray data (94 K). The density maxima on all bonds are significant. The central bond with an internuclear distance of 1.594 Å has a strong bending character. From the difference densities a bending angle of 28° can be derived. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
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页码：341 / 343
页数：3
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