STEREOCONTROLLED SYNTHESIS OF CALYCULIN-A - CONSTRUCTION OF THE C(1)-C(14) TETRAENE NITRILE UNIT

被引：38

作者：

BARRETT, AGM ^{[1
]}

EDMUNDS, JJ ^{[1
]}

HENDRIX, JA ^{[1
]}

HORITA, K ^{[1
]}

PARKINSON, CJ ^{[1
]}

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 17期

关键词：

D O I：

10.1039/c39920001238

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An enantioselective and geometrically selective synthesis of the C(1)-C(14) tetraene nitrile unit of calyculin A, using aldol chemistry with (+)-(E)-diisopinocampheylborane and Stille coupling, is described.

引用

页码：1238 / 1240

页数：3

共 24 条

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