REACTANT ADSORPTION IN ANALYTICAL PULSE VOLTAMMETRY - METHODOLOGY AND RECOMMENDATIONS - (TECHNICAL REPORT)

被引：56

作者：

VANLEEUWEN, HP

BUFFLE, J

LOVRIC, M

机构：

[1] UNIV GENEVA, CH-1211 GENEVA 4, SWITZERLAND

[2] RUDJER BOSKOVIC INST, CTR MARINE RES, YU-41001 ZAGREB, CROATIA

来源：

PURE AND APPLIED CHEMISTRY | 1992年 / 64卷 / 07期

关键词：

D O I：

10.1351/pac199264071015

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This report surveys the effects that arise in pulse voltammetric analysis if the reactant is adsorbed at the electrode/solution interface. Modifications of normal and differential pulse polarograms are outlined. Suitable methodology is developed on the basis of available theory and experimental evidence. The report is concluded with guide-lines for detecting reactant adsorption as well as recommendations for properly dealing with them in practical analytical situations.

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页码：1015 / 1028

页数：14

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