EFFECTIVE RUTHENIUM-CATALYZED OXIDATION OF CHLORINATED OLEFINS BY MONOPERSULFATE IN AQUEOUS-MEDIUM

被引：6

作者：

BRESSAN, M ^{[1
]}

FORTI, L ^{[1
]}

MORVILLO, A ^{[1
]}

机构：

[1] UNIV PADUA,DIPARTIMENTO CHOM INORGAN MET ORGAN & ANALIT,I-35131 PADUA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 03期

关键词：

D O I：

10.1039/c39940000253

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In aqueous medium, in the presence of a surfactant agent and of catalytic amounts of ruthenium derivatives, monopersulfate effectively oxidizes alpha-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 turnover min(-1) at room temperature.

引用

页码：253 / 254

页数：2