FACILE SYNTHETIC ROUTE TO CONE-SHAPED PHOSPHORYLATED [CH2P(O)PH(2)] CALIX[4]ARENES

被引：42

作者：

DIELEMAN, C

LOEBER, C

MATT, D

DECIAN, A

FISCHER, J

机构：

[1] ECOLE EUROPEENE HAUTES ETUD IND CHIM STRASBOURG,CHIM INORGAN MOLEC GRP,F-67008 STRASBOURG,FRANCE

[2] UNIV STRASBOURG 1,CRISTALLOCHIM & CHIM STRUCT LAB,F-67070 STRASBOURG,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 18期

关键词：

D O I：

10.1039/dt9950003097

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Selective incorporation of one, two or four CH2P(O)Ph(2) substituents at specific sites in para-tert-butylcalix[4]arene was achieved using NaH and an appropriate alkylating agent; the tetrasubstituted compound (structure established by X-ray crystallography) was quantitatively reduced to the corresponding tetraphosphine L(6) which, by reaction with [{Pd(C(6)H(4)CH(2)NMe(2)-o)Cl}(2)], gave access to the tetranuclear complex [{Pd(C(6)H(4)CH(2)NMe(2)-o)Cl}(4)L(6)].

引用

收藏

页码：3097 / 3100

页数：4

相关论文

共 28 条

[1] DIRECT REGIOSELECTIVE FORMYLATION OF TETRAALKOXYCALIX[4]ARENES FIXED IN THE CONE CONFORMATION AND SYNTHESIS OF NEW CAVITANDS [J].

ARDUINI, A ;

FANNI, S ;

MANFREDI, G ;

POCHINI, A ;

UNGARO, R ;

SICURI, AR ;

UGOZZOLI, F .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (05) :1448-1453

[2] SELECTIVE ALKALI-METAL CATION COMPLEXATION BY CHEMICALLY MODIFIED CALIXARENES .4. EFFECT OF SUBSTITUENT VARIATION ON THE NA+/K+ SELECTIVITY IN THE ESTER SERIES AND X-RAY CRYSTAL-STRUCTURE OF THE TRIFLUOROETHYL ESTER [J].

ARNAUDNEU, F ;

BARRETT, G ;

CREMIN, S ;

DEASY, M ;

FERGUSON, G ;

HARRIS, SJ ;

LOUGH, AJ ;

GUERRA, L ;

MCKERVEY, MA ;

SCHWINGWEILL, MJ ;

SCHWINTE, P .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1992, (07) :1119-1125

[3] VERSATILE CATION COMPLEXATION BY A CALIX[4]ARENE TETRAAMIDE(L) - SYNTHESIS AND CRYSTAL-STRUCTURE OF [ML][CLO4](2)CENTER-DOT-NMECN (M=FE-II, NI-II, CU-II, ZN-II OR PB-II) [J].

BEER, PD ;

DREW, MGB ;

LEESON, PB ;

OGDEN, MI .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (08) :1273-1283

[4] CALIXARENES, MACROCYCLES WITH (ALMOST) UNLIMITED POSSIBILITIES [J].

BOHMER, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :713-745

[5] SYNTHESIS, COMPLEXATION, AND MEMBRANE-TRANSPORT STUDIES OF 1,3-ALTERNATE CALIX[4]ARENE-CROWN-6 CONFORMERS - A NEW CLASS OF CESIUM SELECTIVE IONOPHORES [J].

CASNATI, A ;

POCHINI, A ;

UNGARO, R ;

UGOZZOLI, F ;

ARNAUD, F ;

FANNI, S ;

SCHWING, MJ ;

EGBERINK, RJM ;

DEJONG, F ;

REINHOUDT, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (10) :2767-2777

[6] TRANSDUCTION OF SELECTIVE RECOGNITION OF HEAVY-METAL IONS BY CHEMICALLY MODIFIED FIELD-EFFECT TRANSISTORS (CHEMFETS) [J].

COBBEN, PLHM ;

EGBERINK, RJM ;

BOMER, JG ;

BERGVELD, P ;

VERBOOM, W ;

REINHOUDT, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (26) :10573-10582

[7] A RHI-CENTERED CAGE COMPOUND WITH SELECTIVE CATALYTIC PROPERTIES [J].

COOLEN, HKAC ;

VANLEEUWEN, PWNM ;

NOLTE, RJM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (07) :905-907

[8] SYNTHESIS AND STRUCTURAL STUDIES ON P-TERT-BUTYL-1,3-DIHYDROXY-2,4-DISULFANYLCALIX[4]ARENE AND ITS MERCURY COMPLEX [J].

DELAIGUE, X ;

HOSSEINI, MW ;

KYRITSAKAS, N ;

DECIAN, A ;

FISCHER, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (06) :609-610

[9]

FIAR CK, 1990, MOLEN INTERACTIVE SY

[10] AGGREGATION OF METAL-IONS WITH FUNCTIONALIZED CALIXARENES - SYNTHESIS AND STRUCTURE OF AN OCTANUCLEAR COPPER(I) CHLORIDE COMPLEX [J].

FLORIANI, C ;

JACOBY, D ;

CHIESIVILLA, A ;

GUASTINI, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (10) :1376-1377