CHIRAL EFFECTS IN THE 2ND-ORDER OPTICAL NONLINEARITY OF A POLY(ISOCYANIDE) MONOLAYER

被引：63

作者：

KAURANEN, M

VERBIEST, T

MEIJER, EW

HAVINGA, EE

TEERENSTRA, MN

SCHOUTEN, AJ

NOLTE, RJM

PERSOONS, A

机构：

[1] EINDHOVEN UNIV TECHNOL,DEPT ORGAN CHEM,5600 MB EINDHOVEN,NETHERLANDS

[2] UNIV GRONINGEN,POLYMER SCI LAB,9747 AG GRONINGEN,NETHERLANDS

[3] UNIV NIJMEGEN,DEPT ORGAN CHEM,6525 ED NIJMEGEN,NETHERLANDS

[4] PHILIPS RES LABS,5600 JA EINDHOVEN,NETHERLANDS

来源：

ADVANCED MATERIALS | 1995年 / 7卷 / 07期

关键词：

D O I：

10.1002/adma.19950070707

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Communication: The influence of chirality on the nonlinear optical properties of poly(isocyanide)s is examined. It is found that the chiral and nonlinear properties can occur on different levels of the molecular structure and can therefore be separately tuned, but that they still can be coupled together. The NLO properties of chiral molecules can also be enhanced significantly by optimizing the magnetic contributions to the nonlinearity, an important result for applications in electro-optics.

引用

页码：641 / 644

页数：4

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