RUTHENIUM FORMYL COMPLEXES AS THE BRANCH POINT IN 2-ELECTRON AND MULTIELECTRON REDUCTIONS OF CO2

被引：58

作者：

TOYOHARA, K ^{[1
]}

NAGAO, H ^{[1
]}

MIZUKAWA, T ^{[1
]}

TANAKA, K ^{[1
]}

机构：

[1] INST MOLEC SCI,OKAZAKI,AICHI 444,JAPAN

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 22期

关键词：

D O I：

10.1021/ic00126a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Both [Ru(bpy)(2)(CO)(CHO)](+) and [Ru(bpy)(trpy)(CHO)](+) (bpy = 2,2'-bipyridine; trpy = 2,2':6',2 ''-terpyridine) were characterized. The latter is a key intermediate in four- and six-electron reductions of CO2 producing HCHO, CH3OH, HOOCCHO, and HOOCCH2OH. The reactivity of these formyl complexes toward CO2 reveals a new pathway of HCOOH formation in electrochemical CO2 reduction.

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页码：5399 / &

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