A NOVEL ROUTE TO METALLACYCLOPROPENE (ETA-2-VINYL) COMPLEXES FROM ALKYNES - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF TRANS-[RECL(=C(CH2PH)CH2)(PH2PCH2CH2PPH2)2][BF4]

被引：58

作者：

POMBEIRO, AJL

HUGHES, DL

RICHARDS, RL

SILVESTRE, J

HOFFMANN, R

机构：

[1] UNIV SUSSEX,AFRC,NITROGEN FIXAT UNIT,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

[2] CNRS,INST RECH CATALYSE,F-69626 VILLEURBANNE,FRANCE

[3] CORNELL UNIV,DEPT CHEM,ITHACA,NY 14853

[4] CORNELL UNIV,CTR MAT SCI,ITHACA,NY 14853

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1986年 / 14期

关键词：

D O I：

10.1039/c39860001125

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1125 / 1127

页数：3

共 23 条

[1]

Albright T.A., 1985, ORBITAL INTERACTIONS

[2] THE ROLE OF METALLACYCLOPROPENES IN THE FORMATION OF ALKYLIDYNE COMPLEXES - EVIDENCE FOR A 1,2-TRIMETHYLSILYL SHIFT AND THE X-RAY CRYSTAL-STRUCTURE OF [MO=C(SIME3)CH2[P(OME)3]2(ETA-5-C9H7)] [J].

ALLEN, SR ;

GREEN, M ;

ORPEN, AG ;

WILLIAMS, ID .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (15) :826-828

[3] SYNTHESIS AND STRUCTURE OF TRANS-[MCL(=C=CHR)(PIPR3)2] (M=RH,IR) - THE 1ST SQUARE-PLANAR VINYLIDENEMETAL COMPLEXES [J].

ALONSO, FJG ;

HOHN, A ;

WOLF, J ;

OTTO, H ;

WERNER, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (05) :406-408

[4] TRANSFORMATION OF A TUNGSTEN(O) ALKYNE TO A TUNGSTEN(II) ALKYNE VIA VINYLIDENE, CARBYNE, AND KETENYL LIGANDS [J].

BIRDWHISTELL, KR ;

TONKER, TL ;

TEMPLETON, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (15) :4474-4483

[5] REVERSIBLE MIGRATION OF A COORDINATED MERCAPTO LIGAND ON TO A METAL-BOUND ALKYNE TO GIVE ETA-2-VINYL COMPLEXES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [WC(CF3).C(CF3)SPRI(CF3C=CCF3)(ETA-5-C5H5)] [J].

CARLTON, L ;

DAVIDSON, JL ;

MILLER, JC ;

MUIR, KW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (01) :11-13

[6] REACTIONS OF ISONITRILE COMPLEXES OF MOLYBDENUM(0) AND TUNGSTEN(0) WITH ALKYLATING-AGENTS TO GIVE CARBYNE (AMINOMETHYNE) COMPLEXES [J].

CHATT, J ;

POMBEIRO, AJL ;

RICHARDS, RL .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 184 (03) :357-364

[7] PROTONATION OF ISONITRILES LIGATING MOLYBDENUM(0) AND TUNGSTEN(0) AT NITROGEN GIVING COMPLEXES OF CARBYNE AND CARBENE LIGANDS [J].

CHATT, J ;

POMBEIRO, AJL ;

RICHARDS, RL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (03) :492-498

[8] THE MECHANISM OF METAL-PROMOTED 1,3-SULFUR SHIFTS INVOLVING THE APPARENT INSERTION OF CARBON-MONOXIDE INTO A CARBON SULFUR BOND [J].

DAVIDSON, JL ;

CARLTON, L .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (15) :964-965

[9] REACTIONS OF SOME IRON AND TUNGSTEN MERCAPTO-COMPLEXES WITH ELECTROPHILIC ACETYLENES LEADING TO NOVEL METALLACYCLES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF THE ETA-2-VINYL COMPLEX [W(ETA-2-C(CF3)C(CF3)-C(O)SME)(CO)2(ETA-5-C5H5)] [J].

DAVIDSON, JL ;

SHIRALIAN, M ;

MANOJLOVICMUIR, L ;

MUIR, KW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (10) :2167-2176

[10] THE MECHANISM OF METAL-PROMOTED ALKYNE CYCLO-OLIGOMERIZATION WITH ISOCYANIDES LEADING TO CYCLOPENTADIENE DERIVATIVES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [WSPRI(CNBUT)(ETA-2-C4(CF3)4CNBUT)(ETA-5-C5H5)] CONTAINING AN ETA-2-TETRAKIS(TRIFLUOROMETHYL)CYCLOPENTADIENIMINE LIGAND [J].

DAVIDSON, JL ;

WILSON, WF ;

MUIR, KW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (08) :460-462

← 1 2 3 →