HYDROBORATION KINETICS .11. A REINVESTIGATION OF THE KINETICS OF HYDROBORATION OF REPRESENTATIVE ALKENES WITH DISIAMYLBORANE DIMER - CONCLUSIVE EVIDENCE FOR THE DISSOCIATION MECHANISM IN THE HYDROBORATION OF ALKENES WITH DIALKYLBORANE DIMERS

被引：21

作者：

CHANDRASEKHARAN, J ^{[1
]}

BROWN, HC ^{[1
]}

机构：

[1] PURDUE UNIV,RICHARD B WETHERILL LAB CHEM,W LAFAYETTE,IN 47907

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1985年 / 50卷 / 04期

关键词：

D O I：

10.1021/jo00204a019

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：518 / 520

页数：3

共 13 条

[1] MECHANISM OF ASYMMETRIC INDUCTION IN HYDROBORATIONS WITH OPTICALLY ACTIVE TETRAISOPINOCAMPHEYLDIBORANE [J].

BROWN, DR ;

KETTLE, SFA ;

MCKENNA, J ;

MCKENNA, JM .

CHEMICAL COMMUNICATIONS, 1967, (14) :667-&

[2] HYDROBORATION .10. RATES OF REACTION OF BIS-3-METHYL-2-BUTYLBORANE WITH REPRESENTATIVE CYCLOALKENES AND ISOMERIC CIS-TRANS ALKENES [J].

BROWN, HC ;

MOERIKOF.AW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (16) :3417-&

[3] HYDROBORATION .15. INFLUENCE OF STRUCTURE ON RELATIVE RATES OF HYDROBORATION OF REPRESENTATIVE UNSATURATED HYDROCARBONS WITH DIBORANE AND WITH BIS-(3-METHYL-2-BUTYL)-BORANE [J].

BROWN, HC ;

MOERIKOF.AW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (14) :2063-&

[4] HYDROBORATION KINETICS .10. KINETICS, MECHANISM, AND SELECTIVITY FOR HYDROBORATION OF REPRESENTATIVE ALKENES WITH BORINANE [J].

BROWN, HC ;

CHANDRASEKHARAN, J ;

NELSON, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (13) :3768-3771

[5] ORGANOBORANES .2. PREPARATION AND PROPERTIES OF ALKYLDIBORANES CONTAINING BULKY ALKYL SUBSTITUENTS [J].

BROWN, HC ;

KLENDER, GJ .

INORGANIC CHEMISTRY, 1962, 1 (02) :204-&

[6] HYDROBORATION .19. REACTION OF DIISOPINOCAMPHEYLBORANE WITH REPRESENTATIVE TRANS + HINDERED OLEFINS ( TRIISOPINOCAMPHEYLDIBORANE AS REAGENT FOR CONFIGURATIONAL ASSIGNMENT OF ALCOHOLS + OLEFINS VIA HYDROBORATION [J].

BROWN, HC ;

AYYANGAR, NR ;

ZWEIFEL, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (06) :1071-&

[7] HYDROBORATION .1. THE REACTION OF OLEFINS WITH SODIUM BOROHYDRIDE ALUMINUM CHLORIDE - A CONVENIENT ROUTE TO ORGANOBORANES AND THE ANTI-MARKOWNIKOFF HYDRATION OF OLEFINS [J].

BROWN, HC ;

RAO, BCS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (24) :6423-6428

[8] UNUSUAL KINETICS FOR THE HYDROBORATION OF ALKENES WITH 9-BORABICYCLO[3.3.1]NONANE [J].

BROWN, HC ;

SCOUTEN, CG ;

WANG, KK .

JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (14) :2589-2591

[9] A NEW POWERFUL REDUCING AGENT - SODIUM BOROHYDRIDE IN THE PRESENCE OF ALUMINUM CHLORIDE AND OTHER POLYVALENT METAL HALIDES [J].

BROWN, HC ;

RAO, BCS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (11) :2582-2588

[10] HYDROBORATION KINETICS - UNUSUAL KINETICS FOR THE REACTION OF 9-BORABICYCLO[3.3.1]NONANE WITH REPRESENTATIVE ALKENES [J].

BROWN, HC ;

WANG, KK ;

SCOUTEN, CG .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA-PHYSICAL SCIENCES, 1980, 77 (02) :698-702

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