A METHOD FOR THE SELECTIVE OXIDATION OF 1,4-DIOLS TO LACTOLS

被引:102
作者
COREY, EJ
PALANI, A
机构
[1] Department of Chemistry, Harvard University, Cambridge
基金
美国国家科学基金会; 美国国家卫生研究院;
关键词
D O I
10.1016/0040-4039(95)00571-S
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Solutions of o-iodoxybenzoic acid in dimethyl sulfoxide at 23 degrees C effect the highly selective oxidation of a number of 1,4-bisprimary or 1,4-primary-secondary diols to gamma-lactols, permitting a conversion which could not previously be accomplished in one step.
引用
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页码:3485 / 3488
页数:4
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