THE EFFECTS OF UV IRRADIATION ON TITANIA DEPOSITION FROM TITANIUM TETRA-ISOPROPOXIDE

被引:4
作者
EGASHIRA, Y
SUGIMACHI, M
NISHIZAWA, K
SAITO, K
OSAWA, T
KOMIYAMA, H
机构
[1] Department of Chemical Engineering, Faculty of Engineering, University of Tokyo, Bunkyo-ku, Tokyo, 113
关键词
D O I
10.1016/0169-4332(94)90442-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of UV irradiation on the deposition of titania from titanium tetra-isopropoxide (TTIP) under reduced pressure was studied. It was found that UV irradiation accelerates the titania growth rate by a factor of 2-3 in the temperature range of 573 to 623 K. The coverage quality of micron-size trenches in the cases with and without UV irradiation indicates the role of the photo-enhanced surface reaction. The threshold wavelength of 380 nm which is equivalent to the energy gap of anatase indicates strongly that band-to-band excitation is responsible for the photo-enhanced surface reaction.
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页码:389 / 392
页数:4
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