SYNTHESIS AND CHARACTERIZATION OF THE FIRST COMPOUNDS CONTAINING A STABLE PHOSPHIRENYL CATION - CRYSTAL-STRUCTURE AND MOLECULAR-STRUCTURE OF [NI(ETA(3)-PC(2)TBU(2))(ETA(5)-P(3)C(2)TBU(2))W(CO)(5)]

被引：42

作者：

AVENT, AG ^{[1
]}

CLOKE, FGN ^{[1
]}

FLOWER, KR ^{[1
]}

HITCHCOCK, PB ^{[1
]}

NIXON, JF ^{[1
]}

VICKERS, DM ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 22期

关键词：

D O I：

10.1002/anie.199423301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cocondensation of Ni vapor with the phosphaalkyne tBuP affords complex 1, which can be substituted at the P3C2 ring with W(CO)5 to give 2. The presence of the first stable phosphirenyl cation was confirmed by spectroscopy and X‐ray crystallography. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2330 / 2332

页数：3

共 25 条

[1] THEORETICAL INVESTIGATIONS ON SOME C2SIH4 ISOMERS
BARTHELAT, JC
TRINQUIER, G
BERTRAND, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (14) : 3785 - 3789
[2] PENTAPHOSPHA AND HEXAPHOSPHA FERROCENES AS LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF [FE(ETA-5-P3C2(T)BU2)2W(CO)5], [FE(ETA-5-P3C2(T)BU2)(ETA-5-P2C3(T)BU3)W(CO)5] AND THE NOVEL TRIRUTHENIUM CARBONYL CLUSTER COMPLEX [FE(ETA-5-P3C2(T)BU2)2RU3(CO)10] CONTAINING 2 INTERLINKED ETA-5-P3C2(T)BU2 RING-SYSTEMS
BARTSCH, R
GELESSUS, A
HITCHCOCK, PB
NIXON, JF
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 430 (01) : C10 - C14
[3] 1ST EXAMPLES OF ETA-1-LIGATED 1,2,4-TRIPHOSPHACYCLOPENTADIENYL RING-SYSTEMS - SYNTHESIS AND FLUXIONAL BEHAVIOR OF TRANS-[MCI(C2R2P3)(PET3)2], (R=BUT,ADAMANTYL),(M=PD,PT) - CRYSTAL AND MOLECULAR-STRUCTURES OF TRANS-[PTX(C2BUT2P3)(PR3)2], (X=CL,R=ET, X=I,R=PH)
BARTSCH, R
CARMICHAEL, D
HITCHCOCK, PB
MEIDINE, MF
NIXON, JF
SILLETT, GJD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (24) : 1615 - 1617
[4] BARTSCH R, 1987, J CHEM SOC CHEM COMM, P1946
[5] CONCERNING PHOSPHIRENIUM CATIONS
BRESLOW, R
DEURING, LA
[J]. TETRAHEDRON LETTERS, 1984, 25 (13) : 1345 - 1348
[6] MOLECULAR-ORBITAL CALCULATIONS ON TRANSITION-METAL COMPLEXES .19. PI-CYCLOPENTADIENYL-PI-CYCLOPROPENYLNICKEL
CLACK, DW
WARREN, KD
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 149 (03) : 401 - 406
[7] SYNTHESIS AND MOLECULAR-STRUCTURE OF TRIS(ETA(4)-2,4-DI-TERT-BUTYL-1,3-DIPHOSPHACYCLOBUTADIENE)MOLYBDENUM(0)
CLOKE, FGN
FLOWER, KR
HITCHCOCK, PB
NIXON, JF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) : 489 - 490
[8] CLOKE FGN, UNPUB
[9] SYNTHESIS OF 1-CHLOROPHOSPHIRENES IN THE COORDINATION SPHERE OF TUNGSTEN
DESCHAMPS, B
MATHEY, F
[J]. TETRAHEDRON LETTERS, 1985, 26 (38) : 4595 - 4598
[10] FORGERS KS, 1983, TETRAHEDRON LETT, V24, P643

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