ENANTIOSELECTIVE CATALYSIS .60. ADDITION OF OPTICALLY-ACTIVE AMINES TO P-SUBSTITUTED OLEFINS

被引:30
作者
BRUNNER, H
LIMMER, S
机构
[1] Institut für Anorganische Chemie, Universität Regensburg, W-8400 Regensburg
关键词
D O I
10.1016/0022-328X(91)80171-F
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The addition of the optically active amines (-)-1-phenylethylamine, (+)-1-phenylethylamine, and (+)-3-aminomethylpinane to diphenylvinylphosphine oxide or 1,1-bis(diphenylphosphino)ethene sulfide gives new PN compounds which were used as cocatalysts in the cross coupling of 1-phenylethyl Grignard with vinylbromide and in the hydrosilylation of acetophenone with diphenylsilane.
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页码:173 / 180
页数:8
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