SYNTHESIS OF GAMMA-KETO-SUBSTITUTED PHOSPHINIC ACIDS FROM BIS(TRIMETHYLSILYL)PHOSPHONITE AND ALPHA,BETA-UNSATURATED KETONES

被引：74

作者：

BOYD, EA

REGAN, AC

JAMES, K

机构：

[1] UNIV KENT,CHEM LAB,CANTERBURY CT2 7NH,KENT,ENGLAND

[2] PFIZER LTD,CENT RES,SANDWICH CT13 9NJ,KENT,ENGLAND

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 06期

关键词：

BIS(TRIMETHYLSILYL)PHOSPHONITE (BTSP); PHOSPHINIC ACIDS; 1,4 MICHAEL-TYPE ADDITION; ADAMANTANAMMONIUM PHOSPHINATES;

D O I：

10.1016/S0040-4039(00)77722-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mono- and di-substituted phosphinic acids have been synthesised in high yield by addition of silyl phosphonites to alpha,beta-unsaturated ketones, and conveniently purified via their adamantanammonium salts.

引用

页码：813 / 816

页数：4

共 5 条

[1] BOYD EA, 1990, TETRAHEDRON LETT, V31, P2933
[2] BOYD EA, 1990, THESIS U KENT CANTER
[3] DIELS-ALDER REACTIONS OF TRANS-1-METHOXY-3-TRIMETHYLSILYLOXY-1,3-BUTADIENE
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[4] USEFUL DIENE FOR DIELS-ALDER REACTION
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[5] BIS(TRIMETHYLSILYL)HYPOPHOSPHITE AND ALKOXYCARBONYLPHOSPHONOUS ACID BIS(TRIMETHYLSILYL)ESTERS AS BUILDING-BLOCKS IN ORGANO-PHOSPHORUS CHEMISTRY
ISSLEIB, K
MOGELIN, W
BALSZUWEIT, A
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 530 (11): : 16 - 28

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