ALLYLIC ALCOHOLS AS SUBSTRATES FOR THE PALLADIUM(0)-CATALYZED ALLYLIC SUBSTITUTION

被引：63

作者：

STARY, I ^{[1
]}

STARA, IG ^{[1
]}

KOCOVSKY, P ^{[1
]}

机构：

[1] UNIV LEICESTER, DEPT CHEM, LEICESTER LE1 7RH, ENGLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(00)60088-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new method has been developed which allows palladium(0)-catalyzed allylic substitution to occur between allylic alcohols and anionic C-nucleophiles: on reaction with Ph3B, the allylic alkoxide 7 is first converted in situ into the more reactive species 8 which then undergoes a Pd(0)-catalyzed reaction with lithiodiethyl malonate via the eta3-complex 9.

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页码：179 / 182

页数：4

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