THE DETERMINATION OF ACTIVITY-COEFFICIENTS AT INFINITE DILUTION USING GLC WITH MODERATELY VOLATILE SOLVENTS (CIS-DECALIN AND TRANS-DECALIN) AT THE TEMPERATURE 298.15-K

被引：4

作者：

LETCHER, TM

BAYLES, JW

MOOLLAN, WC

机构：

[1] Department of Chemistry and Applied Chemistry, Natal University, Durban

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1994年 / 26卷 / 06期

关键词：

D O I：

10.1006/jcht.1994.1065

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The methods recently developed by our group for the determination of activity coefficients by g.l.c. for systems involving moderately volatile solvents (by relating the loss of solvent to its partial pressure) is used in this work to determine the activity coefficients for pentane, cyclopentane, hexane, cyclohexane, benzene, and heptane in cis- and trans -decahydronapthalene (decalin) at the temperature 298.15 K. © 1994 Academic Press Ltd.

引用

收藏

页码：571 / 576

页数：6

相关论文

共 19 条

[11] MEASUREMENT OF GAMMA-INFINITY USING GAS-LIQUID CHROMATOGRAPHY .3. RESULTS FOR THE STATIONARY PHASES 10-NONADECANONE, N-FORMYLMORPHOLINE, 1-PENTANOL, M-XYLENE, AND TOLUENE [J].

KNOOP, C ;

TIEGS, D ;

GMEHLING, J .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1989, 34 (02) :240-247

[12] ACCURATE MEASUREMENT OF ACTIVITY-COEFFICIENTS AT INFINITE DILUTION BY INERT-GAS STRIPPING AND GAS-CHROMATOGRAPHY [J].

LEROI, JC ;

MASSON, JC ;

RENON, H ;

FABRIES, JF ;

SANNIER, H .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1977, 16 (01) :139-144

[13] APPLICATION OF THE PRIGOGINE-FLORY-PATTERSON THEORY .1. MIXTURES OF NORMAL-ALKANES WITH BICYCLIC COMPOUNDS, BENZENE, CYCLOHEXANE AND NORMAL-HEXANE [J].

LETCHER, TM ;

BAXTER, RC .

JOURNAL OF SOLUTION CHEMISTRY, 1989, 18 (01) :65-80

[14] ACTIVITY-COEFFICIENTS OF THE TETRAMETHYL COMPOUNDS OF GROUP-14 ELEMENTS IN NORMAL-ALKANE SOLUTIONS FROM GLC MEASUREMENTS [J].

LETCHER, TM ;

BAXTER, RC ;

BEAN, A ;

SEWRY, JD .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1988, 20 (05) :581-587

[15]

LETCHER TM, 1989, J SOLUTION CHEM, V18, P90

[16]

LETCHER TM, 1978, CHEM THERMODYNAMICS, V2, pCH2

[17] APPARATUS FOR MEASUREMENT OF SECOND VIRIAL COEFFICIENTS OF VAPOURS - SECOND VIRIAL COEFFICIENTS OF SOME N-ALKANES AND OF SOME MIXTURES OF N-ALKANES [J].

MCGLASHAN, ML ;

POTTER, DJB .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1962, 267 (1331) :478-&

[18] THERMODYNAMIC PROPERTIES OF INFINITELY DILUTED SOLUTIONS OF HYDROCARBONS IN POLAR SOLVENTS [J].

VERNIER, P ;

RAIMBAUL.C ;

RENON, H .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1969, 66 (03) :429-&

[19]

WEAST RC, 1984, CRC HDB CHEM PHYSICS, pF66