KINETICS OF THE TRANSFER OF ACETYLCHOLINE ACROSS THE WATER + SUCROSE 1,2-DICHLOROETHANE INTERFACE - A COMPARISON BETWEEN ION-TRANSPORT AND ION TRANSFER

被引：83

作者：

SHAO, Y

GIRAULT, HH

机构：

[1] Department of Chemistry, University of Edinburgh, West Mains Road

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 282卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(91)85090-C

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The transfer of acetylcholine across the water/1,2-dichloroethane interface has been studied as a function of the viscosity of the aqueous phase. The main conclusion of this work is that the standard rate constant is inversely proportional to the viscosity and it is shown that the main difference between ion transfer and ion transport is the consequence of an entropy effect. © 1990.

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页码：59 / 72

页数：14

相关论文

共 17 条

[1] CHRONOCOULOMETRY - A CONVENIENT, RAPID AND RELIABLE TECHNIQUE FOR DETECTION AND DETERMINATION OF ADSORBED REACTANTS [J].

ANSON, FC ;

OSTERYOUNG, RA .

JOURNAL OF CHEMICAL EDUCATION, 1983, 60 (04) :293-296

[2]

BARD AJ, 1980, ELECTROCHEMICAL METH, P204

[3] TRANSFER MECHANISM OF TETRAALKYLAMMONIUM IONS ACROSS A WATER-NITROBENZENE INTERFACE AND THE STRUCTURE OF THE DOUBLE-LAYER [J].

DEPENOUX, B ;

SETA, P ;

AMBLARD, G ;

GAVACH, C .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1979, 99 (01) :77-84

[4]

GAVACH C, 1971, CR ACAD SCI C CHIM, V273, P489

[5] TRANSFER OF TETRA-N-ALKYLAMMONIUM IONS FROM WATER TO NITROBENZENE - CHRONOPOTENTIOMETRIC DETERMINATION OF KINETIC-PARAMETERS [J].

GAVACH, C ;

DEPENOUX, B ;

HENRY, F .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1975, 64 (01) :107-115

[6] THE POTENTIAL DEPENDENCE OF THE RATE OF ION TRANSFER-REACTIONS ACROSS A LIQUID LIQUID INTERFACE [J].

GIRAULT, HH .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 257 (1-2) :47-55

[7] THERMODYNAMIC SURFACE EXCESS OF WATER AND IONIC SOLVATION AT THE INTERFACE BETWEEN IMMISCIBLE LIQUIDS [J].

GIRAULT, HH ;

SCHIFFRIN, DJ .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 150 (1-2) :43-49

[8] THEORY OF THE KINETICS OF ION TRANSFER ACROSS LIQUID LIQUID INTERFACES [J].

GIRAULT, HHJ ;

SCHIFFRIN, DJ .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1985, 195 (02) :213-227

[9]

GIRAULT HHJ, 1989, ELECTROANAL CHEM, V15, P1

[10] A.C. POLAROGRAPHIC STUDY OF ION TRANSFER AT THE WATER NITROBENZENE INTERFACE [J].

OSAKAI, T ;

KAKUTANI, T ;

SENDA, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (02) :370-376