SYNTHESES AND PROPERTIES OF THE 1ST OCTAHEDRAL DIORGANONICKEL(IV) COMPOUNDS

被引：59

作者：

KLEIN, HF

BICKELHAUPT, A

JUNG, T

CORDIER, G

机构：

[1] Eduard-Zintl-Institut für Anorganische Chemie, Technischen Hochschule Darmstadt, D-64289 Darmstadt

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Iodomethane oxidatively substitutes trimethylphosphine in Ni(OC=O)(PMe3)3 (OC=O = 3-tert-butyl-5-methyl-2-oxobenzoyl (1) 3,5-di-tert-butyl-2-oxobenzoyl (2)) to afford the complexes mer-trans-Ni(Me)I(OC=O)(PMe3)2 (3 and 4, respectively). Both compounds undergo a regioselective C,C-coupling reaction in solution and in the crystal state, caused by thermal activation.

引用

页码：2557 / 2559

页数：3

共 13 条

[11] STABILIZATION OF HIGH OXIDATION-STATES BY RIGID BIDENTATE NITROGEN LIGANDS - SYNTHESIS AND CHARACTERIZATION OF DIORGANOPALLADIUM AND TRIORGANOPALLADIUM(IV) AND CATIONIC TRIORGANOPLATINUM(IV) COMPLEXES [J].