SYNTHESIS, AND SPECTRAL AND X-RAY STRUCTURAL STUDIES OF A NOVEL DELOCALIZED TRIPHOSPHAZENE (CF3)2P=N=P(CF3)2=N=PPH3 AND THE TRIOSMIUM CLUSTER COMPLEX OS3(CO)11[(CF3)2P=N=P(CF3)2=N=PPH3]

被引：7

作者：

ANG, HG

CAI, YM

KWIK, WL

机构：

[1] Department of Chemistry, National University of Singapore, Singapore, 0511, Lower Kent Ridge Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 448卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80088-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The triphosphazene (CF3)2P=N=P(CF3)2=N=PPh3 (L), prepared by the reaction of (CF3)PN3 with (CF3)2P=N=PPh3, has bee found to afford the cluster [Os3(CO)11{(CF3)2P=N=P(CF3)2=N=PPh3}] (1) with [Os3(CO)11(MeCN)]. Both L and 1 have been show by X-ray crystallography to have an unusual and highly delocalised P=N=P=N=P moiety containing P(IV), P(V) and P(VI) atoms.

引用

页码：219 / 223

页数：5

共 6 条

[1] FORMATION OF A NOVEL DELOCALIZED DIPHOSPHAZENE UPON COMPLEXATION - THE PREPARATION AND X-RAY STRUCTURE OF PD2CL4[(CF3)2P=N=PPH3]2 [J].