DIACETYLENE-CONTAINING POLYMERS .3. POLY(M,M'-BUTADIYNYLENESUCCINDIANILIDE) AND POLY(M,M'-BUTADIYNYLENE SEBACODIANILIDE) - NOVEL MATERIALS FOR PREPARATION OF TRANSPARENT POLYDIACETYLENE CONTAINING FILMS

被引：13

作者：

FOMINE, S ^{[1
]}

OGAWA, T ^{[1
]}

机构：

[1] NATL AUTONOMOUS UNIV MEXICO,INST INVEST MAT,APARTADO POSTAL 70-360,COYOACAN,MEXICO CITY 04510,DF,MEXICO

来源：

POLYMER JOURNAL | 1994年 / 26卷 / 01期

关键词：

POLYDIACETYLENE; DIACETYLENES; POLYAMIDES; OXIDATIVE POLYCOUPLING; 3-ETHYNYL ANILINE;

D O I：

10.1295/polymj.26.93

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

New bis-acetylenic monomers; succin(m-ethynyl)dianilide and sebaco(m-ethynyl)dianilide were synthesized and polymerized by oxidative polycoupling to give high molecular weight semicrystalline polymers. These polymers were found to be highly light sensitive and turned blue on UV-irradiation to give transparent blue films with absorption maximum beyond 600 nm. The polymers were found to be rather stable on heating and thermal cross-linking via diacetylene groups took place only above 170-degrees-C.

引用

页码：93 / 97

页数：5

共 12 条

[1] FACILE SYNTHESIS OF ETHYNYLATED BENZOIC-ACID DERIVATIVES AND AROMATIC-COMPOUNDS VIA ETHYNYLTRIMETHYLSILANE [J].

AUSTIN, WB ;

BILOW, N ;

KELLEGHAN, WJ ;

LAU, KSY .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (11) :2280-2286

[2]

BURILLO G, 1986, POLYM BULL, V16, P257

[3]

Chemia D. S., 1987, NONLINEAR OPTICAL PR

[4]

ESTRADA MR, 1992, POLYM ADVAN TECHNOL, V3, P419

[5]

KUHLING S, 1990, MACROMOLECULES, V23, P4192

[6] SYNTHESIS AND CHARACTERIZATION OF SOLUBLE, HIGH-MOLECULAR-WEIGHT POLY(AROMATIC DIACETYLENES) [J].

KWOCK, EW ;

BAIRD, T ;

MILLER, TM .

MACROMOLECULES, 1993, 26 (11) :2935-2940

[7] ON THE PHOTOREACTIVITY OF DIACETYLENE CONTAINING THERMOPLASTIC BLOCK COPOLYMERS [J].

LIANG, RC ;

REISER, A .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1987, 25 (02) :451-465

[8] Evaluation of Nonlinear Optical Susceptibility of Polydiacetylenes by Third-Harmonic Generation [J].

Nakanishi, H. ;

Matsuda, H. ;

Okada, S. ;

Kato, M. .

POLYMERS FOR ADVANCED TECHNOLOGIES, 1990, 1 (01) :75-79

[9]

NEYRA R, 1992, 28TH C MEX QUIM PUR, P60

[10] DIACETYLENE CONTAINING POLYMERS .1. POLY(M,M'-BUTADIYNYLENE DIBENZYLTEREPHTHALATE) [J].

PEREZ, J ;

BURILLO, G ;

ROA, M ;

VAZQUEZ, C ;

OGAWA, T .

POLYMER BULLETIN, 1992, 27 (05) :527-534

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