MAIN-GROUP CHEMISTRY WITHIN MACROCYCLIC RINGS AND BASKETS

被引：9

作者：

KHASNIS, DV

BURTON, JM

MCNEIL, JD

ZHANG, HM

LATTMAN, M

机构：

[1] Department of Chemistry, Southern Methodist University, Dallas

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 87卷 / 1-4期

基金：

美国国家科学基金会;

关键词：

CYCLEN; CALIX[4]ARENE; HYPERVALENT; MACROCYCLE; PHOSPHORANE; PHOSPHORANIDE;

D O I：

10.1080/10426509408037443

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The incorporation of main-group elements into macrocycles leads to stabilization of novel structures and control of reactivity. The tetraamino macrocycle cyclen appears to favor a pentacoordinate trigonal bipyramidal (tbp) geometry about phosphorus, even when phosphorus is bonded to transition-metals. The tbp geometry is also favored for arsenic. The tetraphenol macrocycle p-tert-butylcalix[4]arene appears to stabilize a hexacoordinate phosphorus geometry under certain conditions: however, pentacoordinate and tricoordinate structures are also found.

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页码：93 / 100

页数：8

相关论文

共 12 条

[1]

ATKINS TJ, 1978, TETRAHEDRON LETT, P5149

[2]

HOLMES RR, 1980, PENTACOORDINATED PHO, V1, pCH2

[3] PUTTING BOTTOMS ON BASKETS - THE 1ST MAIN-GROUP-ELEMENT SINGLE-ATOM BRIDGE OF A CALIXARENE [J].

KHASNIS, DV ;

LATTMAN, M ;

GUTSCHE, CD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (25) :9422-9423

[4] DIRECT TRANSFORMATION OF 6-COORDINATE TO 3-COORDINATE PHOSPHORUS IN PARA-TERT-BUTYLCALIX[4]ARENE - THE 1ST X-RAY CRYSTAL-STRUCTURE OF A HYPERVALENT MAIN GROUP ATOM BOUND TO A CALIXARENE [J].

KHASNIS, DV ;

BURTON, JM ;

LATTMAN, M ;

ZHANG, HM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (08) :562-563

[5] 1ST STRUCTURAL EVIDENCE FOR TRANS-ANNULAR P-N BONDING IN THE PHOSPHINE FORM OF CYCLENPHOSPHORANE - AN OPEN TAUTOMER [J].

KHASNIS, DV ;

LATTMAN, M ;

SIRIWARDANE, U ;

CHOPRA, SK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (08) :3103-3105

[6] TETRAAZA MACROCYCLIC DERIVATIVES OF ARSENIC - HCYCLENAS, HCYCLENAS.GAME3, AND HCYCLAMAS [J].

KHASNIS, DV ;

ZHANG, HM ;

LATTMAN, M .

ORGANOMETALLICS, 1992, 11 (11) :3748-3753

[7] PHOSPHORANIDE LIGANDS WITH VARIABLE COORDINATION MODES - SYNTHESIS, PROPERTIES, AND X-RAY CRYSTAL-STRUCTURES OF [(ETA-2-HCYCLENP)PT(CL)PPH3]BF4 AND [(H2CYCLENP)PTCL2PPH3]CL [J].

KHASNIS, DV ;

LATTMAN, M ;

SIRIWARDANE, U .

INORGANIC CHEMISTRY, 1989, 28 (04) :681-686

[8] THE 1ST N-ONLY-BONDED METAL DERIVATIVES OF CYCLENPHOSPHORANE - FORMATION OF CYCLENPH.MCL2 AND CYCLENPH.HMCL3 (M = ZN, CD) [J].

KHASNIS, DV ;

LATTMAN, M ;

SIRIWARDANE, U .

INORGANIC CHEMISTRY, 1990, 29 (02) :271-274

[9] REACTION OF CYCLENPHOSPHORANE WITH CIS-DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINUM(II) - FORMATION OF BIDENTATE AND MONODENTATE PHOSPHORANIDE ADDUCTS AND X-RAY CRYSTAL-STRUCTURE OF (ETA-2-CYCLENP)PTCLPPH3 [J].

LATTMAN, M ;

BURNS, EG ;

CHOPRA, SK ;

COWLEY, AH ;

ARIF, AM .

INORGANIC CHEMISTRY, 1987, 26 (12) :1926-1929

[10]

LATTMAN M, 1988, INORG CHEM, V27, P3013