A CONVENIENT HIGH-YIELD SYNTHESIS OF SOME TITANIUM(IV) OXO CLUSTER COMPOUNDS - CRYSTAL-STRUCTURE OF [TI3CL3(MU-O2CC6H4ME-P)5(MU-O)(MU-3-O)]

被引：13

作者：

BASHALL, A ^{[1
]}

BROWN, DA ^{[1
]}

MCPARTLIN, M ^{[1
]}

WALLBRIDGE, MGH ^{[1
]}

机构：

[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 16期

关键词：

D O I：

10.1039/dt9920002529

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of TiCl4 with a series of para-substituted benzoic acids (p-XC6H4CO2H; X = Me, Et, F or l) yields the new trinuclear oxo clusters [Ti3Cl3(mu-O2CCH4X-p)5(mu-O)(mu-O)] in good yield; p-Bu(t)C66H4CO2H gives [{[TiCl(O2CR)2]2O}n] but p-MeOC6H4CO2H yields only a black intractable tar.

引用

页码：2529 / 2530

页数：2

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