SOME REACTIONS OF [(ETA-6-C6ME6)RU(ETA-6-[2.2]PARACYCLOPHANE)]-[BF4]2 WITH NUCLEOPHILES

被引：7

作者：

STEED, JW ^{[1
]}

TOCHER, DA ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 412卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86093-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single addition of the nucleophiles X- (X = H, CN, OH) to the less sterically hindered ring in [(eta-6-C6Me6)Ru(eta-6-C16H16)][BF4]2 (1) proceeds smoothly to produce, as the sole product, [(exo-eta-5-C6Me6X)Ru(eta-6-C16H16)][BF4]. Use of Na[BD4] in place of Na[BH4] gives the expected shift in nu(C-H(exo)) in the infrared spectrum.

引用

页码：C37 / C39

页数：3

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