THE DISSECTION OF BUCKMINSTERFULLERENE INTO CYCLOCARBONS

被引：2

作者：

CRANE, JD

机构：

[1] School of Chemistry, University of Hull, Hull

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1994年 / 2卷 / 03期

关键词：

D O I：

10.1080/15363839408009552

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cyclocarbons C(n) are potential precursors for the controlled synthesis of specific fullerenes. The dissection of buckminsterfullerene (I(h)-C60) into monocyclic rings shows that the I(h)-C60 cage can indeed be formed from such rings without invoking any bond breaking/rearrangement processes. The closure of cyclo-C60 to I(h)-C60 can be achieved in sixteen distinct ways, whereas the dimerisation and closure of cyclo-C30 has a unique geometry.

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页码：291 / 301

页数：11

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