ASYMMETRIC-SYNTHESIS OF HOMOPROPARGYLIC ALCOHOLS FROM ALDEHYDES AND ALLENYLTRI-N-BUTYLSTANNANE

被引：94

作者：

KECK, GE

KRISHNAMURTHY, D

CHEN, X

机构：

[1] Department of Chemistry University of Utah, Salt Lake City

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 45期

关键词：

D O I：

10.1016/S0040-4039(00)74397-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of allenyltri-n-butylstannane with aldehydes and a chiral Lewis acid prepared from (R)-BINOL and Ti(O-i-Pr)(4) gives homopropargylic alcohols with 82 - >99% ee.

引用

页码：8323 / 8324

页数：2

共 5 条

[1] A PRACTICAL AND GENERAL ENANTIOSELECTIVE SYNTHESIS OF CHIRAL PROPA-1,2-DIENYL AND PROPARGYL CARBINOLS
COREY, EJ
YU, CM
LEE, DH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (02) : 878 - 879
[2] CATALYTIC ASYMMETRIC-SYNTHESIS OF HOMOALLYLIC ALCOHOLS
COSTA, AL
PIAZZA, MG
TAGLIAVINI, E
TROMBINI, C
UMANIRONCHI, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (15) : 7001 - 7002
[3] CATALYTIC ASYMMETRIC ALLYLATION (CAA) REACTIONS .2. A NEW ENANTIOSELECTIVE ALLYLATION PROCEDURE
KECK, GE
GERACI, LS
[J]. TETRAHEDRON LETTERS, 1993, 34 (49) : 7827 - 7828
[4] CATALYTIC ASYMMETRIC ALLYLATION REACTIONS .3. EXTENSION TO METHALLYLSTANNANE, COMPARISON OF PROCEDURES, AND OBSERVATION OF A NONLINEAR EFFECT
KECK, GE
KRISHNAMURTY, D
GRIER, MC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (24) : 6543 - 6544
[5] CATALYTIC ASYMMETRIC ALLYLATION OF ALDEHYDES
KECK, GE
TARBET, KH
GERACI, LS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) : 8467 - 8468

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