BICYCLOANNULATION OF ALPHA-BROMO ALPHA,BETA-UNSATURATED ESTERS - SYNTHESIS OF THE TRICYCLO[4.4.0.0(1,5)]DECANE FRAMEWORK AND ITS CONGENERS

被引：17

作者：

HAGIWARA, H

ABE, F

UDA, H

机构：

[1] Institute for Chemical Reaction Science, Tohoku University, Katahira, Aoba-ku

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 21期

关键词：

D O I：

10.1039/p19930002651

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of the kinetic enolates 6 of 1-acetylcyclohexenes 5 with alpha-bromo alpha,beta-unsaturated esters proceed via a successive Michael-Michael-substitution pathway to give methyl 2-oxotricyclo-[4.4.0.0(1,5)]decane-5-carboxylates 8 in a one-pot operation.

引用

页码：2651 / 2655

页数：5

共 25 条

[11] CONSIDERATIONS ON THE EFFECT OF A CARBONYL GROUP ON THE RING-OPENING OF A NEIGHBORING BROMONIUM ION [J].