SYNTHESIS AND PROPERTIES OF NEW PERFLUORINATED ALIPHATIC ISOCYANIDES

被引：4

作者：

KRUMM, B ^{[1
]}

KIRCHMEIER, RL ^{[1
]}

SHREEVE, JM ^{[1
]}

机构：

[1] UNIV IDAHO,DEPT CHEM,MOSCOW,ID 83844

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 11期

关键词：

D O I：

10.1021/ic00115a048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perfluoroazaalkenes R(f)N=CF2 (Rf=CF3, C2F5 C3F7) react with triphenylphosphane to give the respective isocyanides R(f)N=C. This reaction provides a more facile route to the previously described CF3N=C and moreover leads to the new isocyanides C2F5N=C and C3F7N=C. Properties and reactions of C2F5N=C and C3F7N=C with oxidizing agents like Cl-2, Br-2, R(f)OCl (R(f)=CF3, (CF3)(3)C, SF5) and CLF are reported.

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页码：3114 / 3116

页数：3

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