CARBENE ADDUCTS OF MAGNESIUM AND ZINC

被引：135

作者：

ARDUENGO, AJ

DIAS, HVR

DAVIDSON, F

HARLOW, RL

机构：

[1] DuPont Central Research, Experimental Station, Wilmington

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 462卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83336-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and characterizations of adducts of dialkylmagnesium and dialkylzinc with nucleophilic carbenes are described. These carbene adducts are available directly from the reaction of the stable nucleophilic carbenes 1,3-dimesitylimidazol-2-ylidene or 1,3-di(1-adamantyl)imidazol-2-ylidene and the dialkylmetal compounds. The X-ray crystal structures of the 1,3-di(1-adamantyl)imidazol-2-ylidene.diethylzinc adduct and 1,3-dimesitylimidazol-2-ylidene.diethylmagnesium are reported. The adamantyl substituted carbene gave a monomeric metal adduct whereas the mesityl substituted carbene shows a structure with bridging alkyl groups.

引用

页码：13 / 18

页数：6

共 28 条

[11] DISTORTIONLESS ENHANCEMENT OF NMR SIGNALS BY POLARIZATION TRANSFER
DODDRELL, DM
PEGG, DT
BENDALL, MR
[J]. JOURNAL OF MAGNETIC RESONANCE, 1982, 48 (02) : 323 - 327
[12] ALKYLIDENEAMIDO-DERIVATIVES OF METALS AND METALLOIDS .6. SYNTHESIS OF ALKYLIDENEAMIDO(CARBENE)RHODIUM(I) COMPLEXES AND RELATED CHEMISTRY - CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-RH[N-C(CF3)2][C(NMECH2)2](PPH3)2
DOYLE, MJ
LAPPERT, MF
MCLAUGHL.GM
MCMEEKIN.J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (14): : 1494 - 1501
[13] (BIS(3-TERT-BUTYLPYRAZOLYL)HYDROBORATO)ZINC ALKYL DERIVATIVES - COMPETITIVE REACTIVITY OF ZN-C AND B-H BONDS
GORRELL, IB
LOONEY, A
PARKIN, G
RHEINGOLD, AL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (10) : 4068 - 4069
[14] SYNTHESIS, PROPERTIES, AND X-RAY CRYSTAL-STRUCTURE OF TRANS-DICHLOROTETRAKIS-(1,3-DIETHYLIMIDAZOLIDIN-2-YLIDENE)RUTHENIUM(II), A NEUTRAL TETRACARBENE-METAL COMPLEX
HITCHCOCK, PB
LAPPERT, MF
PYE, PL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (16) : 644 - 646
[15] CARBENE COMPLEXES .20. ELECTRON-RICH CARBENEIRON(0) TRIGONAL BIPYRAMIDAL CARBONYLS AND THEIR GERMANIUM(II) AND TIN(II) ANALOGS [FE(CO)3(L)(L')] (L = CN(ME)(CH2)2NME, L' = PET3, 3 COS EQUATORIAL - OR L = M(OAR)2 (EQUATORIAL-M = GE OR SN, AR = C6H2BUT2-2,6-ME-4), L' = CO)
HITCHCOCK, PB
LAPPERT, MF
THOMAS, SA
THORNE, AJ
CARTY, AJ
TAYLOR, NJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 315 (01) : 27 - 44
[16] THE SYNTHESIS AND PROPERTIES OF THE TRANSANNULARLY BONDED ELECTRON-RICH OLEFIN DERIVED FROM 1,4,8,11-TETRA-AZACYCLOTETRADECANE - X-RAY CRYSTAL-STRUCTURE OF THE CHELATING CIS-DICARBENERHODIUM(I) SALT OBTAINED THEREFROM
HITCHCOCK, PB
LAPPERT, MF
TERREROS, P
WAINWRIGHT, KP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (24) : 1180 - 1181
[17] CARBENE COMPLEXES .16. SYNTHESIS AND PROPERTIES OF NN'N''N'''-TETRA-ARYL-SUBSTITUTED ELECTRON-RICH OLEFIN-DERIVED CARBENERUTHENIUM(II) COMPLEXES CONTAINING A SPONTANEOUSLY FORMED ORTHO-METALLATED-N-ARYLCARBENE LIGAND .16. CRYSTAL AND MOLECULAR-STRUCTURES OF [RUCL(CN(C6H4ME-4)CH2CH2NC6H3ME-4)(PET3)2](6) AND [RU(CO)CL(CN(C6H4ME-4)CH2CH2NC6H3ME-4)(PET3)2](16)TA
HITCHCOCK, PB
LAPPERT, MF
PYE, PL
THOMAS, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (12): : 1929 - 1942
[18] CRYSTAL AND MOLECULAR STRUCTURE OF A TETRACARBONYL(CARBENE)IRON COMPLEX
HUTTNER, G
GARTZKE, W
[J]. CHEMISCHE BERICHTE-RECUEIL, 1972, 105 (08): : 2714 - &
[19] THE ION RADICAL SALT OF 1-METHYL-3-PROPYLIMIDAZOLIUM WITH 7,7,8,8-TETRACYANO-PARA-QUINODIMETHANE - MPI+.TCNQ-
LANGER, V
HUML, K
RECK, G
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1982, 38 (JAN) : 298 - 300
[20] CARBENE COMPLEXES .17. CRYSTAL-STRUCTURE OF TRANS-TETRACARBONYL-BIS(1,3-DIMETHYLIMIDAZOLIDIN-2-YLIDENE)MOLYBDENUM(0),TRANS-[MO(CO)4-[CN(ME)CH2CH2NME]2], STRUCTURAL COMPARISON WITH THE CIS-ISOMER, AND A KINETIC-STUDY OF THE TRANS-]CIS ISOMERIZATION
LAPPERT, MF
PYE, PL
ROGERS, AJ
MCLAUGHLIN, GM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (03): : 701 - 704

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