CONVERSION OF NONCONJUGATED DIENES INTO CONJUGATED DIENE-ZIRCONOCENES VIA MULTIPOSITIONAL REGIOISOMERIZATION

被引:35
作者
MAYE, JP [1 ]
NEGISHI, E [1 ]
机构
[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907
关键词
D O I
10.1016/S0040-4039(00)79155-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of n-Bu2ZrCp2 with non-conjugated dienes (1) containing a mono- or 1,2-disubstituted alkene at one end and a 1,1,-di- or trisubstituted alkene at the other gives conjugated diene-zirconocenes 2 via multipositional regioisomerization.
引用
收藏
页码:3359 / 3362
页数:4
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