Multilayer rheology: A comparison of experimental data with modeling of multilayer shear flow

被引:7
作者
Carriere, CJ
Ramanathan, R
机构
[1] Materials Science and Development Laboratory Central Research and Development, Dow Chenical Company, Midland, Michigan
关键词
D O I
10.1002/pen.760352410
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The theological behavior of multilayer polymeric structures has been investigated. Measurements of the bulk viscoelastic properties via small-amplitude oscillatory rheometry indicated that the shear viscosity is independent of both the number of layers (83 vs. 165) and the composition (30/70, 50/50, and 70/30 PC/PMMA by weight) within the limits of the data obtained. It is also apparent that the shear viscosity is influenced strongly by the skin layer material. In addition, a model has been developed that can be used to predict the shear viscosity and sheat stress of a multilayer structure experiencing shear now. The model predicts that the sheat viscosity of a multilayer structure should be independent of the number of layers and strongly dependent on the material in the skin layer. These predictions are in agreement with experimental data.
引用
收藏
页码:1979 / 1984
页数:6
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