A HEMERYTHRIN MODEL COMPLEX WITH CATALASE ACTIVITY

被引：45

作者：

MAUERER, B

CRANE, J

SCHULER, J

WIEGHARDT, K

NUBER, B

机构：

[1] RUHR UNIV BOCHUM, LEHRSTUHL ANORGAN CHEM, POSTFACH 102148, W-4630 BOCHUM, GERMANY

[2] UNIV HEIDELBERG, INST ANORGAN CHEM, W-6900 HEIDELBERG, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1002/anie.199302891

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic disproportionation of H2O2 to O2 and H2O is achieved with the asymmetric hemerythrin model complex 1, which has a reactive coordination site. The catalytic cycle proceeds via the oxyhemerythrin form with a coordinated hydrogenperoxo ligand. L  1,4,7‐trimethyl‐1,4,7‐triazacyclononane, bpy  2,2′‐bipyridine. (Formula Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：289 / 291

页数：3

共 18 条

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