THE EFFECT OF REACTOR SURFACES ON SINGLE-ELECTRON TRANSFER-REACTIONS - THE REACTION OF 1-IODO-2,2-DIMETHYLHEXANE WITH LITHIUM ALUMINUM DEUTERIDE

被引：5

作者：

ASHBY, EC

WELDER, CO

机构：

[1] School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 40期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(95)01486-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of 1-iodo-2,2-dimethylhexane (4) with LiAlD4 have been carried out in a variety of reaction vessels. In vessels of used pyrex, tenon, and stainless steel, the surface of the reactor plays a role in the product distribution. However, treated pyrex, new pyrex and quartz vessels yield consistent data that support single electron transfer as the major reaction pathway in the reduction of 4 with LiAlD4.

引用

页码：7171 / 7174

页数：4

共 6 条

[1] SINGLE-ELECTRON TRANSFER, A MAJOR REACTION PATHWAY IN ORGANIC-CHEMISTRY - AN ANSWER TO RECENT CRITICISMS [J].