SYNTHESIS AND CHARACTERIZATION OF OSMIUM CARBONYL FLUORIDES

被引：33

作者：

BREWER, SA ^{[1
]}

HOLLOWAY, JH ^{[1
]}

HOPE, EG ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 07期

关键词：

D O I：

10.1039/dt9940001067

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The oxidative fluorination of [Os3(CO)12] with XeF2 in anhydrous HF afforded, in solution, cis-[Os(CO)4F2] as the major product with [Os(CO)5F]+, [Os2(CO)7F4] and [Os2(CO)8F3]+ as minor products, all of which have been characterised by C-13, F-19 and C-13{F-19} NMR spectroscopies. Removal of the HF solvent in vacuo yielded the tetrameric [{Os(CO)3F2}4].

引用

页码：1067 / 1071

页数：5

共 30 条

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