RECEPTORS FOR THE HYDRAZINIUM ION - SIMULTANEOUS 1ST-SPHERE AND 2ND-SPHERE COORDINATION INSIDE ORGANOPALLADIUM CROWN-ETHER COMPLEXES

被引：27

作者：

KICKHAM, JE ^{[1
]}

LOEB, SJ ^{[1
]}

机构：

[1] UNIV WINDSOR,DEPT CHEM & BIOCHEM,WINDSOR N9B 3P4,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 24期

关键词：

D O I：

10.1039/c39930001848

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organopalladium crown ether complexes are employed to bind the hydrazinium ion, [NH2NH3]+, via simultaneous first- and second-sphere coordination featuring sigma-donation to Pd and hydrogen bonding to aliphatic ether oxygen atoms.

引用

页码：1848 / 1850

页数：3

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