RECEPTORS FOR THE HYDRAZINIUM ION - SIMULTANEOUS 1ST-SPHERE AND 2ND-SPHERE COORDINATION INSIDE ORGANOPALLADIUM CROWN-ETHER COMPLEXES

被引：27

作者：

KICKHAM, JE ^{[1
]}

LOEB, SJ ^{[1
]}

机构：

[1] UNIV WINDSOR,DEPT CHEM & BIOCHEM,WINDSOR N9B 3P4,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 24期

关键词：

D O I：

10.1039/c39930001848

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organopalladium crown ether complexes are employed to bind the hydrazinium ion, [NH2NH3]+, via simultaneous first- and second-sphere coordination featuring sigma-donation to Pd and hydrogen bonding to aliphatic ether oxygen atoms.

引用

页码：1848 / 1850

页数：3

共 16 条

[11] HIGH-OXIDATION-STATE PENTAMETHYLCYCLOPENTADIENYL TUNGSTEN HYDRAZINE AND HYDRAZIDO COMPLEXES AND CLEAVAGE OF THE N-N BOND [J].

SCHROCK, RR ;

GLASSMAN, TE ;

VALE, MG ;

KOL, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (05) :1760-1772

[12] CLEAVAGE OF THE N-N BOND IN A HIGH-OXIDATION-STATE TUNGSTEN OR MOLYBDENUM HYDRAZINE COMPLEX AND THE CATALYTIC REDUCTION OF HYDRAZINE [J].

SCHROCK, RR ;

GLASSMAN, TE ;

VALE, MG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (02) :725-726

[13]

STODDART JF, 1990, CATION BINDING MACRO, P631

[14]

VANDOORN AR, 1992, RECL TRAV CHIM PAY B, V111, P421

[15] COCOMPLEXATION OF NEUTRAL GUESTS AND ELECTROPHILIC METAL-CATIONS IN SYNTHETIC MACROCYCLIC HOSTS [J].

VANSTAVEREN, CJ ;

VANEERDEN, J ;

VANVEGGEL, FCJM ;

HARKEMA, S ;

REINHOUDT, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (15) :4994-5008

[16]

Veeger C., 1984, ADV NITROGEN FIXATIO

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