LIQUID-LIQUID-EXTRACTION STUDIES OF METAL-IONS WITH DITHIACROWN COMPOUNDS

被引：17

作者：

GLOE, K

MUHL, P

BEYER, L

MUHLSTADT, M

HOYER, E

机构：

[1] TH LEIPZIG,SEKT NAT WISSENSCH,DDR-7030 LEIPZIG,GER DEM REP

[2] KARL MARX UNIV,SEKT CHEM,DDR-7010 LEIPZIG,GER DEM REP

来源：

SOLVENT EXTRACTION AND ION EXCHANGE | 1986年 / 4卷 / 05期

关键词：

IONS; -; Extraction;

D O I：

10.1080/07366298608917900

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The extraction properties of dibenzo-1,10-dithiacrown-6 compounds have been investigated. Especially thiophilic metals are effectively extracted. The extraction of Ag(I), Pd(II) and Au(III) is much greater than that of Hg(II) or Cu(I). Alkali and alkaline earth metals are not extracted. The experimental results show the coordination of metal ions with sulfur is decisive for the extraction. Synergistic extraction is observed for silver and mixtures of dithiacrown compounds and HDEHP, n-caprylic acid or TBP.

引用

页码：907 / 925

页数：19

共 35 条

[31]

SEVDIC D, 1974, P ISEC LYON, P2733

[32] SYNERGISTIC SOLVENT-EXTRACTION OF CROWN ETHER COMPLEXES WITH ALKALI-METAL PICRATES BY NEUTRAL DONOR SOLVENTS [J].

TAKEDA, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1983, 56 (09) :2589-2590

[33]

TAKEDA Y, 1984, HOST GUEST COMPLEX C, V3, P1

[34]

WEBER E, 1982, HOST GUEST COMPLEX C, V1, P1

[35] CROWN ETHERS FOR CHEMICAL-ANALYSIS - A REVIEW [J].

YOSHIO, M ;

NOGUCHI, H .

ANALYTICAL LETTERS PART A-CHEMICAL ANALYSIS, 1982, 15 (15) :1197-1276

← 1 2 3 4 →