CHEMICAL-PROCESSING IN HIGH-PRESSURE AQUEOUS ENVIRONMENTS .1. HISTORICAL-PERSPECTIVE AND CONTINUING DEVELOPMENTS

被引:79
作者
SEALOCK, LJ [1 ]
ELLIOTT, DC [1 ]
BAKER, EG [1 ]
BUTNER, RS [1 ]
机构
[1] PACIFIC NW LAB, RICHLAND, WA 99352 USA
关键词
D O I
10.1021/ie00020a001
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Use of high-temperature pressurized liquid water has been investigated as a reaction medium for conducting chemical reactions and conversion. Results of these studies have demonstrated that high-temperature pressurized liquid water, especially in the presence of suitable catalysts, has unique chemical and physical properties. An overview of fundamental investigations and processing considerations in this environment is presented including details regarding the effects of temperature, pressure, and catalysis. The reactivities of various feedstocks tested are discussed along with the development and scale-up of high-pressure reactor systems used to investigate the process chemistry and engineering. Several new processing concepts were developed for gasification, destruction, and gas processing based on these findings.
引用
收藏
页码:1535 / 1541
页数:7
相关论文
共 45 条
[1]  
AMIN S, 1975, APR AER DIV AM SOC M
[2]  
ANTAL MJ, 1987, ENERGY BIOMASS WASTE, V10, P865
[3]  
BAKER E, 1991, 3RD ANN S ENV PROT E
[4]   CATALYTIC DESTRUCTION OF HAZARDOUS ORGANICS IN AQUEOUS WASTES - CONTINUOUS REACTOR SYSTEM EXPERIMENTS [J].
BAKER, EG ;
SEALOCK, LJ ;
BUTNER, RS ;
ELLIOTT, DC ;
NEUENSCHWANDER, GG ;
BANNS, NG .
HAZARDOUS WASTE & HAZARDOUS MATERIALS, 1989, 6 (01) :87-94
[5]  
BAKER EG, 1988, PNL64912 PAC NW LAB
[6]  
BAKER EG, 1988, 5TH P NAT C HWHM 88, P459
[7]  
BAKER EG, 1989, FY PNL6784 PAC NW LA
[8]  
BUTNER RS, 1987, DBIOTECHNOLOGY BIOEN, V17, P169
[9]  
BUTNER RS, 1987, AQUATIC PLANTS WATER, P739
[10]  
COPA WM, 1989, STANDARD HDB HAZARDO