CHEMICAL-PROCESSING IN HIGH-PRESSURE AQUEOUS ENVIRONMENTS .1. HISTORICAL-PERSPECTIVE AND CONTINUING DEVELOPMENTS

被引：79

作者：

SEALOCK, LJ ^{[1
]}

ELLIOTT, DC ^{[1
]}

BAKER, EG ^{[1
]}

BUTNER, RS ^{[1
]}

机构：

[1] PACIFIC NW LAB, RICHLAND, WA 99352 USA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1993年 / 32卷 / 08期

关键词：

D O I：

10.1021/ie00020a001

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Use of high-temperature pressurized liquid water has been investigated as a reaction medium for conducting chemical reactions and conversion. Results of these studies have demonstrated that high-temperature pressurized liquid water, especially in the presence of suitable catalysts, has unique chemical and physical properties. An overview of fundamental investigations and processing considerations in this environment is presented including details regarding the effects of temperature, pressure, and catalysis. The reactivities of various feedstocks tested are discussed along with the development and scale-up of high-pressure reactor systems used to investigate the process chemistry and engineering. Several new processing concepts were developed for gasification, destruction, and gas processing based on these findings.

引用

页码：1535 / 1541

页数：7

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