HIGHLY REGIO-SPECIFIC AND STEREO-SPECIFIC PREPARATION OF A NEW CARBOHYDRATE-BASED 1,3-OXAZIN-2-ONE BY THE INIR METHOD AND ITS APPLICATIONS IN SOME ASYMMETRIC TRANSFORMATIONS

被引：19

作者：

BANKS, MR

CADOGAN, JIG

GOSNEY, I

GAUR, S

HODGSON, PKG

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] BP INT LTD,RES & ENGN CTR,SUNBURY TW16 7LN,MIDDX,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(00)80392-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Preliminary experiments show that a new gulonic acid-derived 1,3-oxazin-2-one, prepared by an intramolecular nitrene insertion reaction (INIR) method, serves to control both asymmetric aldol and Diels-Alder reactions with excellent stereo-selection.

引用

页码：2447 / 2458

页数：12

共 13 条

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