NEW LATENT ORGANOTIN CATALYSTS - PREPARATION AND MECHANISM OF THE THERMAL-DECOMPOSITION OF BIS(2-(ACYLOXY)ALKYL)DIORGANOTINS

被引:14
作者
JOUSSEAUME, B [1 ]
GOURON, V [1 ]
MAILLARD, B [1 ]
PEREYRE, M [1 ]
FRANCES, JM [1 ]
机构
[1] RHONE POULENC RECH,F-69192 ST FONS,FRANCE
关键词
D O I
10.1021/om00118a073
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New organotin compounds, bis(2-(acyloxy)-alkyl)diorganotins, can be thermally decomposed into diorganotin dicarboxylates. The substituent effects on the reaction parameters are studied, and a possible mechanism for the decomposition is proposed. These tetraorganotins can be regarded as latent catalysts for silicone curing and polyurethane preparation. © 1990, American Chemical Society. All rights reserved.
引用
收藏
页码:1330 / 1331
页数:2
相关论文
共 27 条
[11]  
KOCHI J, 1978, ORGANOMETALLIC MECHA, P249
[12]  
LALIBERTE BR, 1966, J ORGANOMET CHEM, V5, P527
[13]   INTERACTION OF THE CARBON-TIN BOND WITH BETA-POSITIVE CHARGE [J].
LAMBERT, JB ;
WANG, GT .
TETRAHEDRON LETTERS, 1988, 29 (21) :2551-2554
[14]   INTERACTION OF THE CARBON-GERMANIUM OR CARBON TIN BOND WITH POSITIVE CHARGE ON A BETA-CARBON [J].
LAMBERT, JB ;
WANG, GT ;
TERAMURA, DH .
JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (23) :5422-5428
[15]   STABILIZATION OF POSITIVE CHARGE BY BETA-SILICON [J].
LAMBERT, JB ;
WANG, GT ;
FINZEL, RB ;
TERAMURA, DH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (25) :7838-7845
[16]  
NOLTES JG, 1958, FUNCTIONALLY SUBSTIT, P59
[17]   ORGANOTIN TEMPLATES IN ORGANIC-REACTIONS .4. MECHANISTIC INVESTIGATION OF DISTANNOXANE-CATALYZED URETHANE FORMATION STUDIED BY SN-119 NMR-SPECTRA [J].
OTERA, J ;
YANO, T ;
OKAWARA, R .
CHEMISTRY LETTERS, 1985, (07) :901-904
[18]  
Rusch TE, 1980, PLASTICS COMPOUNDING, V3, P61
[19]  
RUSCH TE, 1980, PLASTICS COMPOUNDING, V3, P66
[20]  
RUSCH TE, 1980, PLASTICS COMPOUNDING, V3, P64