THIANICKELACYCLES BY RING-OPENING REACTIONS OF CYCLIC THIOETHERS AND THEIR SUBSEQUENT CARBONYLATION TO THIOESTERS

被引：46

作者：

MATSUNAGA, PT ^{[1
]}

HILLHOUSE, GL ^{[1
]}

机构：

[1] UNIV CHICAGO,DEPT CHEM,SEARLE CHEM LAB,CHICAGO,IL 60637

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 17期

关键词：

D O I：

10.1002/anie.199417481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A functional model for the nickel‐containing CO‐dehydrogenase? Oxidative addition reactions of ethylene sulfide, propylene sulfide, and thietane with nickel complexes like 1 yield thianickelacycles. Formally analogous to the biosynthesis of acetyl coenzyme A, 2 undergoes an insertion reaction with CO followed by reductive elimination of the thiobutyrolactone 3. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1748 / 1749

页数：2

共 23 条

[1] LIGAND SUBSTITUTION VS LIGAND ADDITION .1. DIFFERENCES IN REACTIVITY BETWEEN 1ST-ROW AND 3RD-ROW TRANSITION-METAL CLUSTERS - REACTIONS OF DIMETHYLAMINE WITH THE SULFIDOMETAL CARBONYL CLUSTERS FE3(CO)9(MU-3-S)2, OS3(CO)9(MU-3-S)2
ADAMS, RD
BABIN, JE
[J]. INORGANIC CHEMISTRY, 1986, 25 (19) : 3418 - 3422
[2] CLUSTER SYNTHESES .13. CHEMISTRY OF SULFIDORUTHENIUM CARBONYL CLUSTERS - SYNTHESIS AND CHARACTERIZATION OF THE NEW UNSATURATED CLUSTERS RU4(CO)11-NLN(MU-4-S)2 (N=0-2,L=PME2PH)
ADAMS, RD
BABIN, JE
TASI, M
[J]. INORGANIC CHEMISTRY, 1986, 25 (25) : 4514 - 4519
[3] THERMAL AND PHOTOASSISTED RING-OPENING OF THIETANE IN A TRIOSMIUM CLUSTER COMPLEX
ADAMS, RD
POMPEO, MP
[J]. ORGANOMETALLICS, 1992, 11 (06) : 2281 - 2289
[4] RING-OPENING REACTIONS OF STRAINED-RING THIOETHERS IN METAL CLUSTER COMPLEXES - PHOTOINDUCED TRANSFORMATION OF THIETANE TO 2-PROPENETHIOLATE IN A TRIOSMIUM CLUSTER COMPLEX
ADAMS, RD
POMPEO, MP
[J]. ORGANOMETALLICS, 1990, 9 (06) : 1718 - 1720
[5] FORMATION OF BUTENETHIOLATE BY THE RING-OPENING OF TETRAHYDROTHIOPHENE BY A TRIOSMIUM CLUSTER COMPLEX
ADAMS, RD
POMPEO, MP
WU, WG
YAMAMOTO, JH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) : 8207 - 8213
[6] The Signer method for determining molecular weights
Clark, EP
[J]. INDUSTRIAL AND ENGINEERING CHEMISTRY-ANALYTICAL EDITION, 1941, 13 : 0820 - 0821
[7] ORGANIC-CHEMISTRY OF SUBVALENT TRANSITION-METAL COMPLEXES .7. DESULFURIZATION OF DIBENZOTHIOPHENE BY NICKEL(0) COMPLEXES - EVIDENCE FOR ELECTRON-TRANSFER IN OXIDATIVE ADDITIONS
EISCH, JJ
HALLENBECK, LE
HAN, KI
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (18) : 2963 - 2968
[8] SYNTHESIS AND CHARACTERIZATION OF N,N'-TETRAMETHYLETHYLENEDIAMIN NICKELACYCLOPROPIONATE
FISCHER, R
NESTLER, B
SCHUTZ, H
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1989, 577 (10): : 111 - 114
[9] NICKELALACTONES FOR SYNTHESIS - SONOCHEMICAL AND BIMETALLIC ACTIVATION OF CROSS-COUPLING REACTIONS WITH ALKYL HALIDES
FISCHER, R
WALTHER, D
BRAUNLICH, G
UNDEUTSCH, B
LUDWIG, W
BANDMANN, H
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 427 (03) : 395 - 407
[10] HAN KI, 1986, ORGANOMETALLIC SYNTH, V3, P112

← 1 2 3 →