VERSATILITY OF THE AZIDO BRIDGING LIGAND IN THE FIRST 2 EXAMPLES OF FERRO-ANTIFERROMAGNETIC ALTERNATING NICKEL(II) CHAINS

被引：59

作者：

RIBAS, J ^{[1
]}

MONFORT, M ^{[1
]}

GHOSH, BK ^{[1
]}

SOLANS, X ^{[1
]}

FONTBARDIA, M ^{[1
]}

机构：

[1] UNIV BARCELONA,DEPT CRISTALLOG & MINERAL,E-08028 BARCELONA,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 23期

关键词：

D O I：

10.1039/C39950002375

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-pot reaction of Ni(ClO4)(2) . 6H(2)O, N,N-dimethylethylenediamine (dmen) or 2-aminoethylpyridine (aep) and NaN3 affords the two [Ni(dmen)(mu-N-3)(2)](n) 1 and [Ni(aep)(mu-N-3)(2)](n) 2 chains with unprecedented alternating end-on and end-to-end bridging loops perpendicular to one another; magnetic susceptibility measurements indicate that they are the first two ferro-antiferromagnetic alternating chains of Ni-II.

引用

页码：2375 / 2376

页数：2

共 17 条

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