NEW UNEXPECTED COORDINATION MODE OF AZIDE ACTING AS A BRIDGING LIGAND BETWEEN NICKEL(II) IONS - SYNTHESIS, CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF [NI(N3)2(2,2-DIMETHYLPROPANE-1,3-DIAMINE)]N, AND INFINITE BIDIMENSIONAL POLYMER

被引：60

作者：

MONFORT, M

RIBAS, J

SOLANS, X

机构：

[1] UNIV BARCELONA,DEPT QUIM INORGAN,DIAGONAL 647,E-08028 BARCELONA,SPAIN

[2] UNIV BARCELONA,DEPT CRISTAL LOG,E-08028 BARCELONA,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 04期

关键词：

D O I：

10.1039/c39930000350

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction between aqueous solutions of Ni(ClO4)2, NaN3 and 2,2-dimethylpropane-1,3-diamine (dmpd) gives blue crystals of the title compound which presents the N3- in a new coordination mode (end-to-end with respect to two Ni(II) and end-on to another Ni(II)), the crystal structure of which reveals a new infinite bidimensional sheet with anomalous magnetic behaviour at low temperature.

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页码：350 / 351

页数：2

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