STUDY OF THE REACTION-RATES AND STRUCTURES OF A PHENOL FORMALDEHYDE RESOL RESIN BY C-13 NMR AND GEL-PERMEATION CHROMATOGRAPHY

被引：38

作者：

KIM, MG ^{[1
]}

AMOS, LW ^{[1
]}

BARNES, EE ^{[1
]}

机构：

[1] WEYERHAEUSER CO,TACOMA,WA 98477

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1990年 / 29卷 / 10期

关键词：

D O I：

10.1021/ie00106a010

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Carbon-13 NMR and aqueous gel permeation chromatography studies were carried out on 10 intermediate samples obtained during the synthesis of a typical phenol-formaldehyde resol wood adhesive resin. Apparent kinetic parameters and an improved description of chemical structures in terms of the degree of polymerization and the degree of branching were obtained. The phenol-formaldehyde resol resin of this study was relatively low in molecular weight and high in branches with terminal o,o-bis(hydroxymethyl)phenol groups. © 1990, American Chemical Society. All rights reserved.

引用

页码：2032 / 2037

页数：6

共 15 条

[1]

FORD WT, 1983, POLYM CHARACTERIZATI

[2] ALKALINE-CATALYZED REACTION OF FORMALDEHYDE AND THE METHYLOLS OF PHENOL - A KINETIC STUDY [J].