ENANTIOSELECTIVE SYNTHESIS OF THE AB RING-SYSTEM OF AKLAVINONE VIA A CHEMOENZYMATIC ROUTE

被引：10

作者：

GUANTI, G ^{[1
]}

RIVA, R ^{[1
]}

机构：

[1] CNR,CTR STUDIO CHIM COMPOSTI CICLOALIFAT & AROMAT,I-16132 GENOA,ITALY

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 22期

关键词：

D O I：

10.1016/0040-4039(95)00645-S

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The AB ring system 2 of aklavinone 1 was obtained using a chemoenzymatic protocol. Key steps are the stereoselective addition of lithium enolate of ethyl acetate to ketone 13 and the intramolecular Friedel-Crafts reaction to give tetralin 17.

引用

页码：3933 / 3936

页数：4

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